YES and No:
I found that the /SS (= /CS) pins are just for superficial completeness part of the SPI pin set.
IMHO they were better exluded from the pinout diagrams as they are no involved in the actual transmission protocols.
This is reflected by the micropython SPI class constructors (see
https://docs.micropython.org/en/latest/ ... e.SPI.html):
Neither machine.SPI() nor machine.SoftSPI() have an option for /CS.
Instead it is your responsibility to create the /CS-Pin programmatically "by hand" like in the example given in docs (see above link), and you have to set
before the (possibly several) SPI transfers and
afterwards.
So the /CS pins (X5 and Y5 with the Pyboard) are just ordinary pins and you can use any other pin for the /CS functionality.
As you assumed, you can use the /CS pins for ordinary input or output as you like, after you constructed the pin objects accordingly. .
If you have only one peripheral circuit connected to a SPI bus you don't need a /CS pin at all. You can connect the /CS pin of the peripheral to GND and that means any SPI activity (via SCK, MISO, MOSI) sends to or receives from that peripheral.
In the manuals of ADC-chips I wrote drivers for this was explicitly mentioned, so the latter may be not always guaranteed.